结构式

CAS：	3144-16-9
分子式：	C10H16O4S
分子量：	232.30
中文名称：	(1S)-7,7-二甲基-2-氧代-二环[2.2.1]庚烷-1-甲磺酸 D-樟脑-10-磺酸 D(-)樟脑磺酸 右旋樟脑磺酸
英文名称：	7,7-dimethyl-2-oxo-, (1S)-Bicyclo[2.2.1]heptane-1-methane sulfonic acid D-Camphor-10-surfonic acid 2-oxo-, (1s,4r)-(+)-10-bornanesulfonic acid
右旋樟脑磺酸性状描述：	该品为白色结晶体或结晶性粉末，不溶于醚，微溶于冰醋酸、乙酸乙酯，在潮湿的空气中易潮解。熔点195-200℃
右旋樟脑磺酸质量标准：	外观 白色或几乎白色结晶性粉末 含量 ≥99.0% 干燥失重 ≤2.0% 灼烧残渣 ≤0.5% 比旋度 [α]20D:+21°-(+23)°(C=5, 1NHCl) 熔点 197℃-200℃
右旋樟脑磺酸用途：	有机合成中间体，拆分剂。

Product Identification
【Product Name】1S-(+)-Camphor-10-sulfonic acid
【Synonyms】D-Camphor-b-sulfonic acid 右旋樟脑磺酸
【CAS】3144-16-9
【Formula】C10H16O4S
【Molecular Weight】232.3
【EINECS】252-817-9
【RTECS】DT5077100
【Beilstein/Gmelin】2809676
【Beilstein Reference】4-11-00-00642
【EC Class】corrosive

Physical ａnd Chemical Properties
【Appearance】White powder.
【Solubility in water】Very soluble
【Melting Point】193~196℃
【Boiling Point】375℃
【Density】1 g/cm3
【Partition Coefficient】1.31

First Aid Measures
【Ingestion】Do NOT induce vomiting. If victim is conscious ａnd alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen ａnd a suitable mechanical device such as a bag ａnd a mask.
【Skin】Get medical aid immediately. Immediately flush skin with plenty of soap ａnd water for at least 15 minutes while removing contaminated clothing ａnd shoes. Wash clothing before reuse. Destroy contaminated shoes.
【Eyes】Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).

Handling ａnd Storage
【Storage】Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. Store protected from moisture.
【Handling】Wash thoroughly after handling. Remove contaminated clothing ａnd wash before reuse. Keep container tightly closed. Do not get on skin or in eyes. Do not ingest or inhale. Use with adequate ventilation. Discard contaminated shoes. Keep from contact with moist air ａnd steam.

Hazards Identification
【Inhalation】Causes chemical burns to the respiratory tract.
【Skin】Causes skin burns.
【Eyes】Causes eye burns.
【Ingestion】May cause severe ａnd permanent damage to the digestive tract. Causes gastrointestinal tract burns.
【EC Risk Phrase】R 34
【EC Safety Phrase】S 26 36/37/39 45
【UN (DOT)】1759

右旋樟脑磺酸Exposure Controls/Personal Protection
【Personal Protection】Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA＇s eye ａnd face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】A respiratory protection program that meets OSHA＇s 29 CFR 1910.134 ａnd ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator＇s use.
【Exposure Effects】Chronic exposure may cause burning sensation, coughing, wheezing, laryngitis, shortness of breath, nausea, headache ａnd vomiting.

Fire Fighting Measures
【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), ａnd full protective gear. During a fire, irritating ａnd highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. Do NOT get water inside containers. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.

Accidental Release Measures
【Small spills/leaks】Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation. Do not get water inside containers.

Stability ａnd Reactivity
【Stability】Stable under normal temperatures ａnd pressures.
【Incompatibilities】Strong oxidizing agents, strong bases, moisture.
【Decomposition】Carbon monoxide, oxides of sulfur, carbon dioxide.

Transport Information
【UN Number】1759
【HS Code】2914 70 90