醛试剂5,5-二甲基-1,3-环己二酮

英文名称: 5,5-Dimethyl-1,3-cyclohexanedione
Dimedone
Dimethyldihydroresorcinol
5,5-dimethyl-3-cyclohexanedione
5,5-dimethyldihydroresorcinol
5,5-dimethylhydroresorcinol

性质描述: 白色至绿黄色针状或柱状结晶。熔点148-149℃。溶于甲醇、乙醇、苯、乙酸及50%醇水混合液。干燥结晶性质稳定，但其溶液甚至在遮光下也能分解氧化。该品溶液遇三氯化铁呈红色。

用途: 5,5-二甲基-1,3-环己二酮可以与醛类形成不溶性的缩合物，而且与不同的醛生成的缩合物熔点不同，与酮类则没有这个性质。这个性质可用于醛类的鉴定，因此醛试剂可用来分离或检验醛类。它还可用作呱啶的催化剂和色层分析试用剂。
 

Product Identification
【Product Name】5,5-Dimethyl-1,3-cyclohexanedione
【Synonyms】Cyclomethone 醛试剂
【CAS】126-81-8
【Formula】C8H12O2
【Molecular Weight】140.18
【EINECS】204-804-4
【RTECS】GV0345000
【RTECS Class】Other
【Merck】13,3268
【Beilstein/Gmelin】471489
【Beilstein Reference】4-07-00-01999

Physical ａnd Chemical Properties
【Appearance】Light yellow - beige - white crystalline powder.
【Solubility in water】Very soluble
【Boiling Point】234
【Vapor Pressure】0.06 (25 C)
【pKa/pKb】5.32 (pKa)
【Partition Coefficient】.15
【Heat Of Vaporization】47.0 kJ/mol
【Heat Of Combustion】-4380 kJ/mol
【Usage】For the separation ａnd identification of aldehydes.

First Aid Measures
【Ingestion】Get medical aid. Wash mouth out with water.
【Inhalation】Remove from exposure to fresh air immediately.
【Skin】Get medical aid. Flush skin with plenty of soap ａnd water for at least 15 minutes while removing contaminated clothing ａnd shoes.
【Eyes】Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper ａnd lower eyelids. Get medical aid.

Handling ａnd Storage
【Storage】Store in a cool, dry place. Store in a tightly closed container.
【Handling】Wash thoroughly after handling. Avoid contact with eyes, skin, ａnd clothing. Do not breathe dust, vapor, mist, or gas.

Hazards Identification
【Ingestion】May cause irritation of the digestive tract. May be harmful if swallowed.
【Inhalation】May cause respiratory tract irritation. May be harmful if inhaled.
【Skin】May cause skin irritation. May be harmful if absorbed through the skin.
【Eyes】May cause eye irritation.
【EC Safety Phrase】S 22 24/25

Exposure Controls/Personal Protection
【Personal Protection】Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Poison Class】4

Fire Fighting Measures
【Flash Point】85
【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), ａnd full protective gear. During a fire, irritating ａnd highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.

Accidental Release Measures
【Small spills/leaks】Vacuum or sweep up material ａnd place into a suitable disposal container.

Stability ａnd Reactivity
【Disposal Code】3
【Stability】No data.
【Incompatibilities】Oxidizing agents.
【Decomposition】Carbon monoxide, carbon dioxide.

Transport Information
【HS Code】2914 29 00